Local quasi-equilibrium description of slow relaxation systems.

نویسندگان

  • I Santamaría-Holek
  • A Pérez-Madrid
  • J M Rubí
چکیده

We present a dynamical description of slow relaxation processes based on the extension of Onsager's fluctuation theory to systems in local quasi-equilibrium. A non-Markovian Fokker-Planck equation for the conditional probability density is derived, and from it we obtain the relaxation equation for the moments. We show that the fluctuation-dissipation theorem can be formulated in terms of the temperature of the system at local quasi-equilibrium which is related to that of the bath by means of a scaling factor revealing lack of thermal equilibrium. Our theory may be applied to a wide variety of systems undergoing slow relaxation. We discuss in particular slow dynamics in glassy systems and Brownian motion in a granular gas.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 120 6  شماره 

صفحات  -

تاریخ انتشار 2004